Since the adoption and strengthening of the Montreal Protocol has led to reductions in the emissions of CFCs, atmospheric concentrations of the most significant compounds have been declining. These substances are being gradually removed from the atmosphere. By 2015, the Antarctic ozone hole would have reduced by only 1 million km² out of 25 (Newman et al., 2004); complete recovery of the Antarctic ozone layer will not occur until the year 2050 or later. Work has suggested that a detectable (and statistically significant) recovery will not occur until around 2024, with ozone levels recovering to 1980 levels by around 2068.[1]
There is a slight caveat to this, however. Global warming from CO2 is expected to cool the stratosphere. This, in turn, would lead to a relative increase in ozone depletion and the frequency of ozone holes. The effect may not be linear; ozone holes form because of polar stratospheric clouds; the formation of polar stratospheric clouds has a temperature threshold above which they will not form; cooling of the Arctic stratosphere might lead to Antarctic-ozone-hole-like conditions. But at the moment this is not clear.
Even though the stratosphere as a whole is cooling, high-latitude areas may become increasingly predisposed to springtime stratospheric warming events as weather patterns change in response to higher greenhouse gas loading. This would cause PSCs to disappear earlier in the season, and may explain why Antarctic ozone hole seasons have tended to end somewhat earlier since 2000 as compared with the most prolonged ozone holes of the 1990s.
The decrease in ozone-depleting chemicals has also been significantly affected by a decrease in bromine-containing chemicals. The data suggest that substantial natural sources exist for atmospheric methyl bromide (CH3Br).[2]
The 2004 ozone hole ended in November 2004, daily minimum stratospheric temperatures in the Antarctic lower stratosphere increased to levels that are too warm for the formation of polar stratospheric clouds (PSCs) about 2 to 3 weeks earlier than in most recent years.[3]
The Arctic winter of 2005 was extremely cold in the stratosphere; PSCs were abundant over many high-latitude areas until dissipated by a big warming event, which started in the upper stratosphere during February and spread throughout the Arctic stratosphere in March. The size of the Arctic area of anomalously low total ozone in 2004-2005 was larger than in any year since 1997. The predominance of anomalously low total ozone values in the Arctic region in the winter of 2004-2005 is attributed to the very low stratospheric temperatures and meteorological conditions favorable for ozone destruction along with the continued presence of ozone destroying chemicals in the stratosphere.[4]
A 2005 IPCC summary of ozone issues observed that observations and model calculations suggest that the global average amount of ozone depletion has now approximately stabilized. Although considerable variability in ozone is expected from year to year, including in polar regions where depletion is largest, the ozone layer is expected to begin to recover in coming decades due to declining ozone-depleting substance concentrations, assuming full compliance with the Montreal Protocol.[5]
Temperatures during the Arctic winter of 2006 stayed fairly close to the long-term average until late January, with minimum readings frequently cold enough to produce PSCs. During the last week of January, however, a major warming event sent temperatures well above normal — much too warm to support PSCs. By the time temperatures dropped back to near normal in March, the seasonal norm was well above the PSC threshold.[6] Preliminary satellite instrument-generated ozone maps show seasonal ozone buildup slightly below the long-term means for the Northern Hemisphere as a whole, although some high ozone events have occurred.[7] During March 2006, the Arctic stratosphere poleward of 60 degrees North Latitude was free of anomalously low ozone areas except during the three-day period from March 17 to 19 when the total ozone cover fell below 300 DU over part of the North Atlantic region from Greenland to Scandinavia.[8]
The area where total column ozone is less than 220 DU (the accepted definition of the boundary of the ozone hole) was relatively small until around 20 August 2006. Since then the ozone hole area increased rapidly, peaking at 29 million km² September 24. In October 2006, NASA reported that the year's ozone hole set a new area record with a daily average of 26 million km² between 7 September and 13 October 2006; total ozone thicknesses fell as low as 85 DU on October 8. The two factors combined, 2006 sees the worst level of depletion in recorded ozone history. The depletion is attributed to the temperatures above the Antarctic reaching the lowest recording since comprehensive records began in 1979.[9][10]
The Antarctic ozone hole is expected to continue for decades. Ozone concentrations in the lower stratosphere over Antarctica will increase by 5%–10% by 2020 and return to pre-1980 levels by about 2060–2075, 10–25 years later than predicted in earlier assessments. This is because of revised estimates of atmospheric concentrations of Ozone Depleting Substances — and a larger predicted future usage in developing countries. Another factor which may aggravate ozone depletion is the draw-down of nitrogen oxides from above the stratosphere due to changing wind patterns.[11]